al_rypal wrote;
I am just at a loss to understand how piping hot food that's put in a properly prepared Kilner jar for a few days can harbour botulism?
cjchambers explained it very well some way up thread. My microbiology is about 30 years out of date and it was never my main subject.
The villain is the bacterium Clostridium botulinum which produces a very potent toxin.
Clostridium botulinum produces spores (as a means of surviving unfavouable conditions) and it's these spores which can survive normal cooking temperatures. The spores only produce the toxin when they start to grow and multiply. The spores will only grow and multiply in the absence of oxygen. They will not grow under acidic conditions, nor will they grow in the presence of high concentrations of sugar. So pickles and preserves are OK. For a similar reason ingesting food contaminated with the spores, apart from very young infants, would be harmless because the acidic conditions that exist in the digestive system prevents them growing. However for foods that need to be canned, C. botulinum is a real problem.
The canning process, once the can has cooled, provides just the anaerobic conditions that the organism needs and great care has to be taken that no spores can survive the process. Hence the need for the 3min at 121°C.
The availability of supermarket ready meals and home freezers has largely meant that home canning has all but disappeared as a means of preserving food. So, thankfully with it, have incidents of Botulism. If done properly it is perfectly safe but it's not easy to monitor on a diy basis. Given that the food is neither as palatable nor as nutritious as freshly prepared or indeed cooked and frozen food, it hardly seems worth the bother.